Detailansicht
Handbook of Metathesis
Three Volumes, 3 Bde
ISBN/EAN: 9783527334247
Umbreit-Nr.: 7511103
Sprache:
Englisch
Umfang: 1608 S., 1500 s/w Illustr., 50 farbige Illustr., 1
Format in cm: 9.5 x 25.2 x 17.8
Einband:
gebundenes Buch
Erschienen am 08.04.2015
Auflage: 2/2015
- Zusatztext
- InhaltsangabeVOLUME ONE - CATALYST DEVELOPMENT AND MECHANISM Preface HighOxidation State Molybdenum and Tungsten Complexes Relevant to Olefin Metathesis Alkane Metathesis Diastereocontrol in Olefin Metathesis: The Development of Z-Selective Ruthenium Catalysts Ruthenium Olefin Metathesis Catalysts Supported by Cyclic Alkyl Aminocarbenes (CAACs) Supported Catalysts and Nontraditional Reaction Media Insights from Computational Studies on d0 Metal-Catalyzed Alkene and Alkyne Metathesis and Relation Reactions Computational Studies of Ruthenium-Catalyzed Olefin Metathesis Intermediates in Olefin Metathesis Factors Affecting Initiation Rates Degenerate Metathesis Mechanisms of Olefin Metathesis Catalyst Decomposition and Methods of Catalyst Reactivation Solvent and Additive Effects on Olefin Metathesis Metathesis Product Purification Ruthenium Indenylidene Catalysts for Alkene Metathesis VOLUE TWO APPLICATIONS IN ORGANIC SYNTHESIS Preface General RingClosing Metathesis CrossMetathesis Vignette: Extending the Application of Metathesis in Chemical Biology - The Development of Site-Selective Peptide and Protein Modifications RutheniumCatalyzed Tandem Metathesis/NonMetathesis Processes Enyne Metathesis Alkyne Metathesis CatalystControlled Stereoselective Olefin Metathesis Two Vignettes: RCM in Natural Product Total Synthesis Metathesis of Silicon-Containing Olefins RingClosing Metathesis in the LargeScale Synthesis of Pharmaceuticals Metathesis Strategies in Diversity-Oriented Synthesis Olefin Metathesis: Commerical Applications and Future Opportunities Index VOLUME THREE - POLYMER SYNTHESIS Preface Synthesis of Homopolymers and Copolymers ROMP in Dispersed Media Telechelic Polymers Supramolecular Polymers Synthesis of Materials with Nanostructured Periodicity Synthesis of Nanoparticles Synthesis of Biodegradable Copolymers Biologically Active Polymers Combination of ROMP with Click Chemistry SelfHealing Polymers Functional Supports and Materials Latent Ruthenium Catalysts for ROMP ADMET Polymerization Biorenewable Polymers Polymerization of Substituted Acetylenes Index
- Kurztext
- The tremendous success of the metathesis reaction over the last decade is reflected in its huge impact on organic, polymer, and organometallic chemistry. It is highly reliable and produces few by-products, making it environmental friendly. Beside its academic use, many industrial applications in petrochemistry, agro- and pharmachemistry, as well as in the field of fine chemicals and material science have been developed and further underscore the importance of this fascinating reaction. This second edition of the "bible" in this field has been completely updated and now features more than 80% new content, with the focus on new developments in the field, especially in industrial applications. No other book covers the topic in such a comprehensive manner and in such high quality. Edited by a Nobel laureate in the field, and with a list of contributors that reads like a "Who's-Who" of metathesis, this is an indispensable one-stop reference for organic, polymer and industrial chemists, as well as chemists working with organometallics.
- Autorenportrait
- Robert H. Grubbs received his Ph.D. from Columbia University for work with Ron Breslow. After a postdoctoral year with Jim Collman at Stanford University, he joined the faculty at Michigan State University. In 1978, he moved to the California Institute of Technology, where he is now the Victor and Elizabeth Atkins Professor of Chemistry. Among many other awards, he received the Nobel Prize in 2005 for his research on the metathesis reaction. His research interests include polymer chemistry, organometallic catalysis, and the development of new synthetic organic methodology. Anna G. Wenzel received her PhD at Harvard University under the guidance of Prof. E. N. Jacobsen. From 2003 to 2006, she joined the group of Prof. R. H. Grubbs as an NIH Postdoctoral Scholar. In 2006, she joined the faculty as an Assistant Professor at the W. M. Keck Science Department in Claremont, California. In 2012, she was promoted to Associate Professor. Her research topics are asymmetric catalysis, organometallic chemistry, and organic synthesis. Daniel J. O?Leary received his PhD at UCLA in the group of Prof. Frank A. L. Anet. Following an NSF postdoctoral fellowship with Prof. Yoshito Kishi at Harvard University, he became Assistant Professor at Pomona College, where he is presently the Carnegie Professor of Chemistry. His research interests are in the area of organic synthesis, isotope effects, and nuclear magnetic resonance. Ezat Khosravi obtained his PhD in Polymer Science from the University of Sussex, UK in 1981. He is presently Reader in Polymer Chemistry at Chemistry Department, Durham University, UK. His research interests range from well-defined polymerization chemistry to novel polymers and biopolymers. He is internationally recognized particularly for his work on Ring Opening Metathesis Polymerization (ROMP) and related chemistry. He is the permanent secretary of the advisory board of the International Symposium on Olefin Metathesis (ISOM).